Australian Gem Gallery - A Rainbow of Gems
Australian Diamonds
The Argyle
Mine and Its Diamonds -
Australias
first commercial diamonds
Adapted from
Chapman, J. et al. (1996)
Australian Gemmologist. 19, 339-346
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Gem quality diamonds from Echunga, South Australia
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Pink-red diamond, Argyle Mine,
Western Australia
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Purplish-red cut diamond,
Argyle Mine,
Western Australia |
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Champagne diamonds, Argyle Mine,
Western Australia
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Rough champagne- coloured diamond
crystal, Argyle Mine, Western Australia
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Uncut rough diamond crystals,
Argyle Mine, Western Australia |
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Introduction
Western Australias Argyle lamproite pipe, the worlds largest producer of
diamond by volume, yields brown, yellowish brown, colourless and red to pink diamonds that
have a dominantly eclogitic paragenesis. Fancy coloured Type 1a Argyle diamonds typically
have a low nitrogen content, mostly in the B-aggregated form. These diamonds are highly
strained, colour zoned parallel to {111}, and mostly contain proto/syngenetic inclusions
that reveal an eclogitic paragenesis.
The
Discovery
Systematic exploration for diamondiferous diatremes in the West Kimberley region of
Western Australia commenced in 1969, following the recovery of nine diamonds from the
Leonard River by Oilmin N.L. exploration geologists. By 1972 the Kalumburu Joint Venture -
consisting of Tanganyika Holdings Ltd, A.O. (Australia) Pty Ltd, Northern Mining
Corporation N.L., Jennings Mining Ltd, and Sibeka Societe DEnterprise et
DInvestissements SA - had been formed for the express purpose of exploring the
Kimberley Region for diamonds above latitude 19° N.
Early 1976 saw the first
successful recovery of kimberlite indicator minerals from routine stream samples taken
from the region. This discovery led CRA Exploration to join with the Kalumburu Joint
Venturers to form the Ashton Joint Venture (AJV).
In August 1979, the AJV
laboratory in Perth reported that two diamonds had been discovered in a sample of gravel
collected from Smoke Creek, a small creek that drained north easterly into Lake Argyle.
Further progressive sampling upstream led to the subsequent discovery of the Lower and
Upper Smoke Creek alluvial deposits, and ultimately, on 2nd October 1979, geologists
walked onto and recognised the potentially diamondiferous AK-1 (Argyle Kimberlite No. 1)
olivine lamproite pipe. Today this pipe is commonly referred to as the Argyle pipe.
The
Argyle Pipe
The Argyle pipe (Fig. 1) is located at the headwaters of Smoke Creek, in a small valley
near the eastern end of the Matsu Range. The pipe is located some 120 km from the nearest
town, Kununurra, 25 km upstream from Lake Argyle, and 2,200 km north-east of Perth. When
first discovered, the Argyle pipe occupied the whole valley floor and had a surface area
of about 45 ha. It had a distinctively linear outcrop with a length of 1,600 m, and a
width that varied from 150 to 600 m.
Subsequent petrological
investigations revealed that the Argyle pipe contained both tuffaceous and magmatic
varieties of lamproite. While the predominantly eclogitic diamonds of the Argyle pipe have
been dated at an estimated 1,580 million years old, these diamonds were emplaced
hydrovolcanically shortly after their formation between 1,100 and 1,200 million years ago.
This relatively short storage time (~ 400 m.y.) and the dominance of B-aggregated nitrogen
indicates the diamonds experienced relatively high temperatures during this time5.
Haggerty hypothesised6
That the existence of a
complex plumbing system below the mobile belt into which the Argyle pipe is emplaced, and
a complex annealing history, could account for the dominantly small, highly modified (by
dissolution), poor quality B-aggregate rich diamonds that commonly occur in the Argyle
pipe.
Having initial proven
reserves of 61 million tonnes or ore, with an average grade of 6.8 ct/tonne, and further
estimated reserves of 14 million tonnes, at a grade of 6.1 ct/ tonne, the Argyle pipe
became the worlds largest volume producer of diamond7. Exploration of the
Argyle pipe and its surrounds was completed when in 1981 a second high-grade deposit of
alluvial diamonds was located on Limestone Creek, a non perennial stream that drains the
Argyle pipe to the south-east.
Rapid evaluation and
development of the Argyle pipe followed; with mining of the diamondiferous Smoke Creek and
Limestone Creek gravels commencing in 1983, and open cut mining of the Argyle pipe
commencing in December 1985. Ten years later, a drilling program, initiated to assess
diamond grade below the planned open pit bottom to about 300 m, revealed a possible
diamondiferous resource of up to 100 million tonnes of ore having an average in situ
diamond content of 3.7 ct/tonne.
Continuing studies into the
future of the Argyle open pit have led to a decision, during June 1998, not to proceed
with underground mining, Instead, a decision was made to cut back the west ridge of the
mine to access additional ore (64 million tonnes with a diamond content of 2.58 ct/tonne)
suitable for open cut mining. Further it has been suggested that underground mining, by
sub-level caving, may come on stream later in the first decade of the 21st century.
Argyle
Diamonds
Over the first fifteen years of the Argyle pipes exploitation as an open cut mine,
annual production has increased substantially and to such an extent that annual production
peaked in 1996 at 42 million carats of which almost 2.7 million carats were derived from
associated alluvial deposits. Despite a small drop in production to 40.8 million carats in
1998, this rate of production has assured that Australia continues to be the worlds
leading producer of diamonds, by volume, but not by value. The reasons for this apparent
contradiction are quite simple. First, the average mix of diamonds in the Argyle pipe
consists of 55 per cent industrial quality diamond, 45 per cent near gem quality diamond,
and only 5 per cent gem quality diamond11. Second, of the small percentage of
the gem quality diamonds recovered from the Argyle mine about 95 per cent are brown and
brownish yellow hued, some 4 per cent are either colourless or grey, and much less than 1
per cent have the very desired pink to red hues. While Argyle diamond sales has little
problem marketing its popular pinks and reds, persistent and innovative marketing has
resulted in ever increasing acceptance for champagne and cognac browns, as
well as markets for small sized diamonds that are cut from near gem rough by labour
intensive Indian manufacturers.
Gemmological
Characteristics
After more than a decade of intensive marketing, and following more than a decade of
intensive research, it is indeed surprising that so little has been published in the
gemmological literature on the characteristics of Argyles brown to yellow, pink and
colourless diamonds.
It is clear that a
significant feature of diamonds from the Argyle pipe is that the majority of them have
suffered deformation of their crystal lattice. In instances where diamonds are plastically
deformed, and their nitrogen content is low, a brown or pink colour is produced.
In an attempt at collating
readily available information on the gemmological characteristics of Argyle diamonds, for
the benefit of gemmologists world-wide, a summary of the typical gemmological
characteristics of Argyle diamonds has been compiled and is presented as table 1.
Table 1
THE TYPICAL GEMMOLOGICAL
CHARACTERISTICS OF ARGYLE DIAMONDS
Gemmological
Characteristics |
Colourless
Diamond |
Brown
Diamond |
Pink-red-mauve
Diamond |
Classification |
Type
1a
Type 11 (rare) |
Type
1a |
Type
1a |
Nitrogen
Content |
500-1,000
ppm |
100-500
ppm |
10-100
ppm |
N
aggregation status |
B-
>>A-aggregates |
B-
>A-aggregates |
A->>B-aggregates |
Habit |
Irregular shapes (<60%), macles (~ 25%), crystal
aggregates (~ 10%), strongly resorbed dodecahedra and octahedra-dodecahedra (~ 5%). Cubes
are rare.
Most Argyle diamonds are
heavily frosted, have prominent etch channels, and have external surfaces patterned with
hexagonal etch pits. |
Colours |
Brown (~ 80%), yellow (16%), colourless (2%), grey (2%),
pink and green (<1%). |
Colour
zoning |
None |
Planar and associated with one or rarely more (111) slip
planes. When examined between crossed polars displays a tatami pattern of
strain birefringence. |
UV
Fluorescence
UV Phosphorescence |
Blue (LWUV>SWUV) due to N3 centre
Yellow |
Dull
green (LWUV>SWUV)
Dull yellow-inert |
Blue (LWUV>SWUV)
Yellow |
X-ray
Fluorescence
X-ray Phosphorescence |
Blue-white
Yellow |
Blue-white
Yellow |
Blue-white
Yellow |
Absorption
Spectra1- Infrared
- Visible
- Ultraviolet |
B-aggregate
absorptions (8.4m >7.8 m )
N3 absorptions
Absorption edge at ~ >230
nm |
Mixed
B- and A-aggregate absorptions (8.4m » 7.8m )
Increasing absorption
towards the blue with superimposed N3 (415.2 nm), N2 (478 nm), and H3 (503.2 nm)
absorptions.
Absorption edge between 230
and 320 nm |
A-aggregate
absorptions (7.8m >8.4m )
A broad absorption centred
at 550 nm, N3 and ?N2 absorptions.
Absorption edge at ~ <320
nm |
Characteristic
Inclusions |
75 %
eclogitic, 10 % peridotitic, 10 % indeterminable
sulphides.
Eclogitic proto/syngenetic
inclusions were orange garnet (57%), garnet + clinopyroxene (16%), omphacitic pyroxene
(6%), kyanite (3%), rutile (2%), coesite (1%), mixtures of rutile-garnet, garnet-sulphide,
garnet-cpx-sulphide, garnet-kyanite, kyanite-sulphide (15%)
Peridotitic proto/syngenetic
inclusions were olivine (45%), pyrope garnet (9%), enstatite (9%), mixtures of
olivine-diopside, olivine-garnet, olivine-garnet-enstatite, enstatite-garnet (37%).
Epigenetic graphite lining
cleavages and fractures is the commonest inclusion in Argyle diamond. |
References:
Argyle Diamond Mines Joint
Venture (1983) Project briefing. 102 p. ADMJV: Perth.
Argyle Diamond Mines Joint
Venture (1985) Project briefing. 95 p. ADMJV: Perth.
Argyle Diamonds (1987)
From the diamonds of Argyle to the champagne jewels of Stewart Devlin. Argyle Diamond
Sales: Perth.
Ashton Mining Limited
(1995) Half yearly report to 30 June, 1995.
Atkinson, W.J. (1989)
Diamond exploration philosophy, practice, and promises: a review.
In Ross, J. Ed.,
Kimberlites and related rocks. vol. 2, Proceedings of the Fourth International Kimberlite
Conference, Perth, 1986. Geological Society of Australia Special Publication No 14. pp.
1075-1107. Blackwell Scientific Publications: Oxford.
Chapman, J. and Humble, P.
(1991) The cause of colour in Argyle pink and champagne diamonds. In
A.S. Keller Ed.
Proceedings of the International Gemological Symposium 1991 p. 159-160.
GIA: Santa Monica.
Fardy, J.J. and Farrar, Y.J. (1992) Trace-element profile of Argyle diamonds using instrumental neutron activation
analysis. Radioanalytical Nuclear Chemistry, Letters. 164 (5), 337-345.
Fritsch, W. and Scarratt,
K. (1992) Natural-color nonconductive gray-to-blue diamonds. Gems &
Gemology. 28,
35-42.
Haggerty, S.E. (1986)
Diamond genesis in a multiply-constrained model. Nature. 320, 34-38.
Hall, A.E. and Smith, C.B.
(1984) Lamproite diamonds - are they different? In Glover, J.E. & Harris,
P.G. Eds.
Kimberlite occurrence and origin. pp. 167-212. Geology Department, University of Western
Australia Publication No. 8. pp. 167-202.
Hofer, S.C. (1985) Pink
diamonds from Australia. Gems & Gemology. 21, 147-155.
Jaques, A.L., Lewis, J.D.
and Smith, C.B. (1986) The kimberlites and lamproites of Western Australia. Geological
Survey of Western Australia Bulletin No. 132. pp. 35, 38-59, 239-246.
Manigan, R. (1983) Diamond
exploration in Australia. Indiaqua. No. 38. pp. 27-38.
Mendelssohn, M.J. and Millidge, H.J. (1995) Geologically significant information from routine analysis of the
mid-infrared spectra of diamonds. International Geology Review. 37, 95-110.
Richardson, S.H., Gurney, J.J., Erlank, A.J. and Harris,
W.J. (1984) Origin of diamonds in old enriched mantle.
Nature. 310, 198-202
Rio Tinto
Zinc-Consolidated Rutile Australia (1996) RTZ-CRA production report for the quarter ending
31 December, 1995.
U.S.A. Bureau of Mines
(1995) Annual review of gemstones. Mineral Industry Reviews. Table 11.
Wilks, J. and E. (1991)
Properties and applications of diamond. pp. 62-94. Butterworth: Heinemann.
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